Methyl 2-[2-(tert-butoxycarbonylamino)-1,3-benzothiazole-6-carboxamido]acetate
نویسندگان
چکیده
In the title compound, C(16)H(19)N(3)O(5)S, the dihedral angle between the benzene ring and the carbonyl-amino group is 18.18 (2)°. In the crystal, mol-ecules form centrosymmetric dimers via pairs of N-H⋯N hydrogen bonds. The dimers are connected via N-H⋯O hydrogen bonds into a three-dimensional network..
منابع مشابه
Methyl 2-(tert-butoxycarbonylamino)-1,3-thiazole-5-carboxylate
The title compound, C(10)H(14)N(2)O(4)S, was synthesized by the reaction of methyl 2-amino-thia-zole-5-carboxyl-ate and di-tert-butyl carbonate. In this structure, the thia-zole ring is planar (mean deviation = 0.0011 Å). Two weak intra-molecular C-H⋯O hydrogen bonds are formed between two of the methyl groups and one carbonyl O atom, resulting in the formation of two twisted six-membered rings...
متن کاملBis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II)
In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octa-hedral coordination environment. The two benzothia-zole-2-thiol-ate ligands chelate via their thia-zole N and thiol-ate S atoms while the methyl 2-(2-amino-thia-zol-4-yl)-2-(methoxy-imino)acetate also acts as a chelate ligand binding through the thia-zole and imino N atoms. ...
متن کاملBis(2-amino-6-methyl-1,3-benzothiazole-κN 3)bis(4-nitrobenzoato-κO 1)zinc
In the title mononuclear complex, [Zn(C(7)H(4)NO(4))(2)(C(8)H(8)N(2)S)(2)], the Zn(II) atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia-zole and by two carboxylate O atoms from two 4-nitro-benzoate ligands, adopting a slightly distorted tetra-hedral coordination geometry. In the crystal, inter-molecular N-H⋯O hydrogen bonds between the amino group of 2-amino-6-methyl-1...
متن کامل2-Amino-6-methyl-1,3-benzothiazole–decanedioic acid (2/1)
Co-crystallization of 2-amino-6-methyl-1,3--benzothia-zole with deca-nedioic acid under hydro-thermal conditions afforded the title 2:1 co-crystal, 2C(8)H(8)N(2)S·C(10)H(18)O(4). The deca-nedioic acid mol-ecule is located on an inversion centre. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds connect the components into a two-dimensional wave-like layer structure extending parall...
متن کامل2-Amino-6-methyl-1,3-benzothiazole–octanedioic acid (2/1)
Cocrystallization of 2-amino-6-methy-1,3-benzothia-zole with octa-nedioic acid in a mixed methanol-water medium afforded the title 2:1 cocrystal, 2C(8)H(8)N(2)S·C(8)H(14)O(4). The octa-nedioic acid mol-ecule is located on an inversion centre. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds connect the components into a three-dimensional network.
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